Geochemical Characteristics of Cenozoic Basaltic High-K Volcanic Rocks from Maguan Area, Eastern Tibet

The major element, trace element and Nd-Sr isotopic composition of Cenozoic basaltic volcanic rocks from the Maguan area, eastern Tibet, indicates that the volcanic rocks are enriched in alkalis, especially K (K-2O up to {3.81%}) and depleted in Ti (TiO-2={1.27%}-{2.00%}). These rocks may be classified as two groups, based on their Mg+# numbers: one may represent primary magma (Mg+# numbers from 68 to 69), and the other, the evolved magma (Mg+# numbers from 49 to 57). Their REE contents are very high (∑REE={155.06}-{239.04}μg/g). Their REE distribution patterns are of the right-inclined type, characterized by LREE enrichment [(La/Yb)-N={12.0}-{19.2}], no Ce anomaly (Ce/Ce+*={1.0}), and weak negative Eu anomaly (Eu/Eu+*={0.9}). The rocks are highly enriched in Rb, Sr and Ba ({59.5}-{93.8} μg/g, 732-999 μg/g, and 450-632 μg/g, respectively), high in U and Th ({1.59}-{2.31} μg/g and {4.73}-{8.16} μg/g, respectively), and high in Nb, Ta, Zr and Hf (70-118 μg/g, {3.72}-{5.93} μg/g, 215-381 μg/g, and {5.47}-{9.03} μg/g, respectively). In the primitive mantle-normalized incompatible element spidergram, Nb, Ta, Zr, Hf and P show positive anomalies, whereas Ba, Ti and Y show negative anomalies. The {{}+{87}Sr/+{86}Sr} ratios range from {0.704029} to {0.704761}; {{}+{143}Nd/+{144}Nd} from {0.512769} to {0.512949}; and εNd from {+2.6} to {+6.1}. These geochemical features might suggest that the potential source of the basaltic high-K volcanic rocks in the Maguan area is similar to the OIB-source mantle of Hawaii and Kergeulen volcanic rocks.