摘要
The IR emission spectra of methane were measured under DC glow discharge conditions. The distinct difference in time between methane decomposition and C2 hydrocarbons formation was specially pointed out. Ca hydrocarbons formed at the end of methane decomposition. The optimum condition for C2 hydrocarbon formation was studied and the optimum combination between electric current density and methane input quantity was suggested. The appropriate reaction conditions for methane decomposition and Ca hydrocarbons formation are different, so high yield of Ca hydrocarbons will be probably obtained when different conditions are taken.
The IR emission spectra of methane were measured under DC glow discharge conditions. The distinct difference in time between methane decomposition and C2 hydrocarbons formation was specially pointed out. C2 hydrocarbons formed at the end of methane decomposition. The optimum condition for C2 hydrocarbon formation was studied and the optimum combination between electric current density and methane input quantity was suggested. The appropriate reaction conditions for methane decomposition and C2 hydrocarbons formation are different, so high yield of C2 hydrocarbons will be probably obtained when different conditions are taken.
基金
Supported by the Special Fund of the Education Committee of Shaanxi Province (No. 2000K13-G19 and No. 2002K09-G21).