开链冠醚类似物研究 Ⅲ 2,2′,2″-三(4-氧安替比林)三乙胺的合成及其Cu(Ⅱ)、Bi(Ⅲ)和Fe(Ⅲ)配合物的制备

Studies on Open-Chain Crown Ether Analogues Ⅲ Synthesis of 2, 2', 2"-Tri ( 4-oxyantipyrine) triethylamine and Preparations of Its Cu ( Ⅱ ), Bi (Ⅲ ) and Fe (Ⅲ) Complexes

采用四种方法,让2,2′,2″-三氯三乙胺盐酸盐与4-羟基安替比林进行0-烷基化反应,合成了一个新的开链窝穴体,2,2′,2″-三（4-氧安替比林）三乙胺（TAEA）,进而制备了它分别与CuCl_2、BiCl_3及Fe（SCN）_3的三个配合物,并测定了TAEA及其配合物的物理常数、元素组成和光谱数据.

A new open-chain cryptand, 2, 2', 2'-tri ( 4-oxyantipyrine) triethylamine (TAEA), was synthesized from reaction between 4-hydroxyantipyrine and 2, 2', 2'-trichlorotriethylamine hydrochloride by way of four methods. Its structure was identified by elemental analysis, IR, 1H NMR and MS. Three complexes of TAEA with CuCl2, BiCl3 and Fe (SCN) 3 were prepared and determined.