摘要
The molar conductance of electrolytes LiPF 6-PC(propylene carbonate), LiPF 6·2DG(diglyme)-PC and LiPF 6·PMDETA(pentamethyldiethylenetriamine)-PC were calculated by using mean spherical approximation(MSA). The range of concentration was from 0.001 mol·L -1 to 1 mol·L -1. The dissociation equilibrium of salts is taken into account. The mean relative deviations were 5.6%, 4.2% and 4.7%, respectively.
The molar conductance of electrolytes LiPF 6-PC(propylene carbonate), LiPF 6·2DG(diglyme)-PC and LiPF 6·PMDETA(pentamethyldiethylenetriamine)-PC were calculated by using mean spherical approximation(MSA). The range of concentration was from 0.001 mol·L -1 to 1 mol·L -1. The dissociation equilibrium of salts is taken into account. The mean relative deviations were 5.6%, 4.2% and 4.7%, respectively.
出处
《化工学报》
EI
CAS
CSCD
北大核心
2004年第2期268-270,共3页
CIESC Journal
基金
清华大学基础研究基金资助项目 (No .2 0 0 115 0 0 7)
关键词
平均球近似理论
电导率
锂盐
有机溶液
mean spherical approximation, conductance, lithium salt, organic solution
