分子对称性与杂化轨道

SYMMETRICAL AND HYBRID ORBITALS

本文通过分子的对称性,用群论方法处理了中心原子轨道的对称性,进而组成σ键的杂化轨道。并对H_2O和NH_3分子中的氧与氮的杂化方式进行了一些讨论。

This paper discussed it possibility that analysing the symmetry of center atom composed the hybrid orbit got the irreducible representation of hybrid orbit by group method,determined the symmetry of each certer atom orbit and then according to the symmetry composed of the hybrid orbit,the hybrid orbit of H_2O and NH_3 were discussed.