含氮外消旋配体金属络合物在苯乙酮不对称氢转移反应中的应用

The use of the catalysts consisting of racemic ligand,transition metal complex and chiral activator in the hydride transfer reduction reaction of acetophenone

本文将(1S,2S)-1,2-二苯基乙二胺、(±)-1,1'-联-2-萘胺以及过渡金属络合物二-μ-氯-二(1,5-环辛二烯)二铑组成的催化剂体系用于催化苯乙酮的不对称氢转移反应,通过气相色谱法及旋光测定法对反应物的转化率及产物的光学纯度进行了分析和测定。

In this thesis the catalyst consisting of racemic ligand、transition metal complex and chiral activator were used to catalyze the hydride transfer reduction reaction of acetophenone in2-propanol.The product was char-acterized and analysized by gas chromatograph and polarimeter.