摘要
Studies of the non-isothermal decomposition of barium2,4,6-trinitroresorecinate monohydrate,Ba(TNR)·H 2 O,were carried out by means of TG-DTA,DSC and IR.The thermal decomposition mechanism and associated ki-netics were investigated.The kinetic parameters were obtained from an analysis of the DSC curves by integral and differential methods.The most probable kinetic model function of the dehydration reaction of Ba(TNR)·H 2 O was suggested by comparison of the kinetic parameters.
Studies of the non-isothermal decomposition of barium2,4,6-trinitroresorecinate monohydrate,Ba(TNR)·H 2 O,were carried out by means of TG-DTA,DSC and IR.The thermal decomposition mechanism and associated ki-netics were investigated.The kinetic parameters were obtained from an analysis of the DSC curves by integral and differential methods.The most probable kinetic model function of the dehydration reaction of Ba(TNR)·H 2 O was suggested by comparison of the kinetic parameters.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2004年第4期412-420,共9页
Chinese Journal of Inorganic Chemistry
基金
陕西省物理无机化学重点实验室科技基金资助项目(No.29鄄3
2001)
国防科工委火炸药燃烧重点实验室预研基金资助项目(No.514550101)。
