碳-碳键型活性自由基聚合引发体系的研究现状

ADVANCE IN CARBON-CARBON BOND TYPE INITIATION SYSTEM FOR ‘LIVING’ RADICAL POLYMERIZATION

与其它引发剂相比,碳-碳键型引发剂由于其自身的优良性能,因而逐渐受到了研究者的重视。本文简要介绍碳-碳键型引发剂在热引发转移终止剂和反向ATRP引发体系中的引发机理,及这两种活性自由基的聚合方法。

Comparing with other initiators, because of the initiation character of carbon-carbon bond type initiator, it has been attracted considerable attention in recent some years. In this paper, the thermal iniferter and reverse atom transfer radical polymerization, which initiated by carbon-carbon bond type initiators, were introduced.