摘要
Modified sensing membranes based on fluorescence quenching were prepared by the sol-gel method,using formamide as the drying control chemical additive,tetraethoxysilane as the main material,Ru(phen) 3Cl 2 as the indicator.The membrane with the optimum thickness of 20-50μm is uniform and crack-free,in which the indicator has a very small leaking rate.The membrane is immersed in water for 50h,the membrane sensing parameter M decreases by less than 5%.The fiber optic oxygen sensor with the sensing membrane has a detection limit of 5×10 -6M(ppm),a response time of less than 30s,excellent reproducibility and stability.
Modified sensing membranes based on fluorescence quenching were prepared by the sol-gel method,using formamide as the drying control chemical additive,tetraethoxysilane as the main material,Ru(phen) 3Cl 2 as the indicator.The membrane with the optimum thickness of 20-50μm is uniform and crack-free,in which the indicator has a very small leaking rate.The membrane is immersed in water for 50h,the membrane sensing parameter M decreases by less than 5%.The fiber optic oxygen sensor with the sensing membrane has a detection limit of 5×10 -6M(ppm),a response time of less than 30s,excellent reproducibility and stability.
基金
FundedbytheNationalNaturalScienceFoundationofChi na(No .6 0 3770 32 ) ,theKeyScientificProjectFoundationofHubeiProvince (No .2 0 0 1AA10 1A0 2 )andNaturalScienceFoundationofHubeiProvince (No .2 0 0 1ABB0 74 )
