摘要
Amino-1,10-phenanthroline and three types of new 5-substituted 1,10-phenanthroline derivatives by different alkyl amides, phen-NHCOR[phen=1,10-phenanthroline; R=CHCH 2; (CH 2) nBr, n=1,3—5; (CH 2) nCH 3, n=9—14], were synthesized. They were characterized by means of elemental analyses, infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, and mass spectroscopy. These new compounds are important ligands or the active materials of ruthenium(Ⅱ) electrochemiluminescent(ECL) sensors.
Amino-1,10-phenanthroline and three types of new 5-substituted 1,10-phenanthroline derivatives by different alkyl amides, phen-NHCOR[phen=1,10-phenanthroline; R=CHCH 2; (CH 2) nBr, n=1,3—5; (CH 2) nCH 3, n=9—14], were synthesized. They were characterized by means of elemental analyses, infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, and mass spectroscopy. These new compounds are important ligands or the active materials of ruthenium(Ⅱ) electrochemiluminescent(ECL) sensors.
基金
Supported by the Natural Science Foundation of Hainan Province(No.80 2 0 3)
