Synthesis and Nonlinear Optical Property of a Polyphosphazene with High Glass Transition Temperature

Synthesis and Nonlinear Optical Property of a Polyphosphazene with High Glass Transition Temperature

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摘要 A new polyphosphazene containing binaphtholyl and indole azo chromophores as side chains with high glass transition temperature ( Tg ) was synthesized by a post-functional method. The polymer was well characterized. Its Tg was tested to be 168℃, and the poled film of P2 reveals a resonant d33 value of 20 pm/V by second harmonic generation ( SHG ) measurements. A new polyphosphazene containing binaphtholyl and indole azo chromophores as side chains with high glass transition temperature ( Tg ) was synthesized by a post-functional method. The polymer was well characterized. Its Tg was tested to be 168℃, and the poled film of P2 reveals a resonant d33 value of 20 pm/V by second harmonic generation ( SHG ) measurements.

作者 ZhenLI JinGuiQIN ZhouYANG ChengYE

机构地区 DepartmentofChemistry CenterforMolecularScience

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2004年第4期489-491,共3页 中国化学快报（英文版）

关键词 POLYPHOSPHAZENE SYNTHESIS SHG. Polyphosphazene, synthesis, SHG.

分类号 O623.761 [理学—有机化学]

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Chinese Chemical Letters

2004年第4期

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Synthesis and Nonlinear Optical Property of a Polyphosphazene with High Glass Transition Temperature

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