期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

环氧丙基杯[6]开环聚合物的合成及其吸附性能 被引量：2

Syntheses and Absorption Properties of Epoxy-propyl Calix-based Polymers
下载PDF
导出
摘要 通过全取代环氧丙基杯[6]芳烃与多乙烯多胺进行开环聚合,合成了系列新型含氨基和羟基的杯[6]芳烃聚合物.研究了它们的阳离子吸附性能后发现,与其他杯芳烃聚合物相比,该类聚合物对软硬金属离子均有强的吸附能力,其离子吸附容量随着多乙烯多胺分子量的增大而缓慢增大. Reacting epoxy-propyl calixarene with poly(ethyleneimine), a series of new calix arene polymers containing amido groups and hydroxyl groups were obtained. It is found that they show high absorption capacities towards both soft cations and hard cations, and the absorption abilities enhanced with the increasing of molecular weight of poly(ethyleneimine) slowly.
作者 蔡秀琴 杨发福 郭红玉 郑思宁
机构地区 福建师范大学化学与材料学院
出处 《福建师范大学学报（自然科学版）》 CAS CSCD 2004年第1期59-61,共3页 Journal of Fujian Normal University：Natural Science Edition
基金 福建省自然科学基金资助项目(E0220002) 福建青年科技人才创新专项资金资助课题(2001J025).
关键词 合成 吸附性能 芳烃聚合物 开环聚合 开环聚合物 Calixarene polymer syntheses absorption
分类号 O632.7 [理学—高分子化学]
  • 相关文献

参考文献2

二级参考文献16

  • 1黄文强,斯志怀,何炳林.3－聚苯乙烯磺酰基环氧丙烷作为活性中间体制备聚合物试剂[J].离子交换与吸附,1995,11(1):85-88. 被引量：1
  • 2Yang F F. Studies on Calix [ 6,8 ] crowns, Biscrowns and Their Derivatives ( in Chinese) [ D ]. Wuhan:Wuhan University ,2001.
  • 3Sun S, Sepaniak M J, Gutsche C D. Capillary Electrokinetic Chromatography Employing p - (carboxyethyl)Callx [ n ] arenes as Running Buffer Additives [ J ]. Anal Chem, 1997,69 : 344 - 346.
  • 4Xing J, Li T, Zhong Z L, et al. Two Stabilized Calix[ 6 ] cryptand Stereo Isomers Used as Stationary Phases for Capillary Gas Chromatography [ J ]. Analytical Sci ,1999,15:785-788.
  • 5Glennon J D, Home E, McKervey M A. Silica - boned Catixarenes in Chromatography: 2. Chromatographic Betention of Metal Ions and Amino Acid Ester Hydrochlorides [ J ]. J Chromatogr, 1996,731 : 47 - 51.
  • 6Shinkai S, Kawaguchi H, Manabe O. Syntheses of p -Chlorosulfonylcalix [ 6 ] arene - based Gels and its Complexation Capabilities towards UO2^+ [ J ]. J Poly Sci,Part C:Poly Lett ,1988,26:391 -392.
  • 7Brindle R, Albert K, Harris S J, et al. Silica - boned Catixarenes in Chromatography : 1. Synthesis and Characterization by Solid - state NMR Spectroscopy[J]. J Chromatography A, 1996,731:41 -46.
  • 8Arnaud-Neu F, Collins E M, Deasy M, et al. Synthesis, X- ray Crystal Structures, and Cation- binding Properties of Alkyl Calixaryl Esters and Ketones, a New Ramily of Macrocyclic Molecular Beceptors[ J]. J Am Chem Soc, 1989,111:8681 - 8691.
  • 9Xu W, Li J S, Chen Y Y. Preparation and Characterization of p - tert - Butylcalix [ 6 ] arene - bonded silic agel Stationary Phase for High - performance Liquid Chromatography [ J ]. Chromatogr, 1998,48:245 - 250.
  • 10Huang W Q,Si Z H,Li C X,et al. Cu^2+ Complexation Properties of Glycin Grafting on Polymer [ J ]. Exchange and Absorption of Ions ( Chinese ), 1997,13(3) :307 -311.

共引文献6

同被引文献16

  • 1杨发福,郭红玉,陈希磊,蔡秀琴.环氧丙基杯[6]-1,4-冠4-聚合物的合成与吸附性能[J].合成化学,2004,12(6):523-525. 被引量：8
  • 2Sun S,Sepaniak M J,Gutsche C D.Capillary Electrokinetic Chromatography Employing p-(Carboxyethyl) calix[n]arenes as Running Buffer Additives[J].Anal Chem,1997,69:344-346.
  • 3Xing J,Li T,Zhong Z L,et al.Two Stabilized Calix[6]cryptand Stereo Isomers Used as Stationary Phases for Capillary Gas Chromatography[J].Analytical Sci,1999,15:785-788.
  • 4Glennon J D,Horne E,McKervey M A.Silica-boned Calixarenes in Chromatography.2.Chromatographic Retention of Metal Ions and Amino Acid Ester Hydrochlorides[J].J Chromatogr,1996,731:47-51.
  • 5Shinkai S,Kawaguchi H,Manabe O.Syntheses of p-Chlorosufonylcalix[6 ]arene-based Gels and Its Complexation Capabilities Towards UO+2[J].J Poly Sci,Part C:Poly Lett,1988,26:391-393.
  • 6Brindle R,Albert K,Harris S J,et al.Silica-boned Calixarenes in Chronatography.l.Synthesis and Characterization by Solid-state NMR Spectroscopy[J].J Chronatography A,1996,731:41-46.
  • 7Yang F F,Guo H Y,Lin J R.Syntheses and Adsorption Propertide of Calix[6] Amide-based Polumers[J].Chin Chem Lett,2003,14 (5):453-455.
  • 8黄璜.[D].武汉:武汉大学,1999:45-46.
  • 9Yang F F, Chen Y Y. Ion complexation properties of Calix[6]arene derivatives:1. 1,4-calix[6]crown-4 derivatives[J].Supramolecular Chem., 2001, 12 (4): 445-446.
  • 10Shinohara T, Wakisaka S, Ohto K, et al..Synthesis of novel type resin based on calix[4]arene carboxylate and selective separation of lead from zinc[J]. Chem. Lett, 2000, 5: 640-641.

引证文献2

二级引证文献8

福建师范大学学报（自然科学版）
2004年 第1期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部