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Synthesis and magnetic properties of one-dimensional Mn(Ⅱ)complexes linked by dithiooxalato 被引量：2

Synthesis and magnetic properties of one-dimensional Mn(II) complexes linked by dithiooxalato
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摘要 Three dithiooxalato (Dto) bridging one-dimensional Mn(Ⅱ) complexes [Mn(L)Dto](L = Phen (1), Bpy (2) and en (3)) were synthesized. All of the complexes have the similar one-dimensional structure through Dto bridge. The measurement of the variable temperature magnetic susceptibility of complex 1 showed that there are weak antiferromag- netic interactions between the Mn(Ⅱ) ions. Three dithiooxalato (Dto) bridging one-dimensional Mn(II) complexes [Mn(L)Dto](L = Phen (1), Bpy (2) and en (3)) were synthesized. All of the complexes have the similar one-dimensional structure through Dto bridge. The measurement of the variable temperature magnetic susceptibility of complex 1 showed that there are weak antiferromag-netic interactions between the Mn(II) ions.
作者 CUI Jianzhong, SHI Wei, CHENG Peng, CHEN Xufang, LIAO Daizheng, YAN Shiping, JIANG Zonghui & WANG GenglinDepartment of Chemistry, Nankai University, Tianjin 300071, China Correspondence should be addressed to Cheng Peng (e-mail: pcheng@ nankai.edu.cn)
出处 《Chinese Science Bulletin》 SCIE EI CAS 2003年第9期859-861,共3页
基金 supported by the National Natural Science Foundation of China(Grant Nos.90101028 and 50173011) the Natural Science Foundation of Tianjin(Grant No.013801611)and the TRAPOYT of MOE,China
关键词 一维结构 锰配合物 合成 反铁磁性 Dto 二硫代草酰胺 one-dimensional, manganese(II), complex, 1,2-dithioox-alato, ESR, magnetism.
分类号 O482.5 [理学—固体物理]
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参考文献10

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Chinese Science Bulletin
2003年 第9期

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