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Structural stability of infinitelayer CaCuO2 under high pressure

Structural stability of infinite-layer CaCuO_2 under high pressure
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摘要 In situ high-pressure energy dispersive X-ray diffraction measurements on polycrystalline powder CaCuO2 with an infinite layer structure (IL CaCuO2) have been performed by using diamond anvil cell (DAC) instrument with synchrotron radiation. The results suggest that the crystal structure of IL CaCuO2 is stable under pressure up to 30 GPa at room temperature. According to Birch-Murn- aghan equation of state, assuming pressure derivative the bulk modulus B0=181 ± 9 GPa is obtained. In situ high-pressure energy dispersive X-ray diffraction measurements on polycrystalline powder Ca-CuO2 with an infinite layer structure (IL CaCuO2) have been performed by using diamond anvil cell (DAC) instrument with synchrotron radiation. The results suggest that the crystal structure of IL CaCuO2 is stable under pressure up to 30 GPa at room temperature. According to Birch-Murn- aghan equation of state, assuming pressure derivative 4,=0Bthe bulk modulus B0=181 ?9 GPa is obtained.
出处 《Chinese Science Bulletin》 SCIE EI CAS 2003年第2期1201-1203,共3页
基金 国家自然科学基金,中国科学院"百人计划"
关键词 结构稳定性 高压能量耗散 无限层CaCuO2 同步加速器辐射 X射线衍射 多晶粉末 DAC 超导电性 infinite-layer CaCuO2, synchrotron radiation, high pressure energy dispersive X-ray diffraction.
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