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Preparation of nanocrystalline Co3O4 and its properties as supercapacitors 被引量:4

Preparation of nanocrystalline Co_3O_4 and its properties as supercapacitors
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摘要 Nanocrystallines Co3O4 with the particle diameter of 3 nm are prepared and tested as active electrode material for an electrochemical supercapacitor. The results of characterization indicate that the grain size of this material is very small; the specific surface area is very high (192 m2/g); the distributions of pore diameter are desirable and effective; furthermore, the agglomeration problem among small particles was solved to a certain extent. The electrochemical tests show that the electrode prepared with the Co3O4 exhibits distinct characteristic of capacitance and very high specific capacitance of 365-401 F/g. Additionally, the main attribute of capacitance, namely supercapacitance, was also testified. Nanocrystallines Co3O4 with the particle di-ameter of 3 nm are prepared and tested as active electrode material for an electrochemical supercapacitor. The results of characterization indicate that the grain size of this mate-rial is very small; the specific surface area is very high (192 m2/g); the distributions of pore diameter are desirable and effective; furthermore, the agglomeration problem among small particles was solved to a certain extent. The electro-chemical tests show that the electrode prepared with the Co3O4 exhibits distinct characteristic of capacitance and very high specific capacitance of 365—401 F/g. Additionally, the main attribute of capacitance, namely supercapacitance, was also testified.
机构地区 DepartmentofChemistry
出处 《Chinese Science Bulletin》 SCIE CAS 2003年第2期1212-1215,共4页
基金 国家自然科学基金
关键词 四氧化三钴 纳米晶体 电气化学电容器 AC阻抗 电极材料 超级电容器 nanocrystallines Co3O4, preparation, electrochemical capacitors, supercapacitance, AC impedance.
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