YⅪ—RuⅩⅥ离子3d^(10)4l(l=s,p,d,f)组态能级的逐插计算方法研究

A Successive-Difference Method for Energy Levels of Configurations 3d^(10)4l(l=s,p,d,f) from YⅪ—RuⅩⅥ

在准相对论HXR方法计算的基础上,分析了等电子序列离子能级结构的特点,提出了一种高剥离态离子能级新的逐插计算方法.计算了Y —Ru 离子3d104l(l=s,p,d,f)组态能级,其结果与已有实验结果相当符合.而Tc 离子的所有能级值纯属预测计算结果.

Based on the results calculated by HXR method, by taking the important relativistic effects into account with the solution of many-body-perturbation (MPB) theory, a new successive difference fit method is put forward. The energy levels of configurations 3d^(10)4l(l=s,p,d,f) in copper-like sequence from YⅪ—RuⅩⅥ is calcuiated. The result shows that the energy levels are in good agreement with the associated experiment data. The levels of TcⅩⅤ are sheer predicted results.