可控自由基聚合与其它活性聚合方法结合制备嵌段共聚物

Synthesis of Block Copolymers by Combination of Controlled Radical Polymerizations and other Polymerizations

可控自由基聚合与其它聚合方法结合 ,可以制备多种类型的嵌段共聚物 ,因此得到了广泛关注。本文着重介绍可控自由基聚合与离子开环聚合、阴离子聚合、烯类单体的阳离子聚合及其它活性聚合方法结合制备嵌段共聚物的研究现状和进展。

Combinations of controlled radical polymerizations and other living polymerizations are applied to synthesize various block copolymers, and this method has received much attention. This article primarily summarizes recent progress in the research on the preparation of block copolymers by combination of controlled radical polymerizations and ionic ring-opening polymerization, anionic polymerization, cationic vinyl polymerization and other living polymerizations.