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一维正交配置法计算甲醇合成平行反应的效率因子 被引量：3

Effectiveness Factors for Parallel Reactions of Methanol Synthesis Calculated by One-Dimensional Orthogonal Collocation Method
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摘要 采用正交配置法计算了CO和CO_2加氢合成甲醇平行反应的效率因子,计算结果与实验数据吻合良好,计算方法有效、迅速。 The effectiveness factors of parallel hydorgenation reactions of CO and CO_2 to form methanol over Cu-based catalyst were calculated by the orthogonal collocation method. The calculated values are well consistent with the experimental results. The calculation is not time-consuming, so that the method is an effective one.
作者 孙启文 房鼎业 朱炳辰
机构地区 华东化工学院化学工程系
出处 《华东化工学院学报》 CSCD 1992年第2期147-152,共6页
关键词 甲醇 合成 平行反应 效率因子 orthogonal collocation methanol synthesis parallel reactions effectiveness factor
分类号 TQ223.121 [化学工程—有机化工]
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同被引文献20

  • 1宋维端 朱炳辰 等.C301铜基催化剂甲醇合成反应动力学（Ⅰ）本征动力学模型[J].化工学报,1988,39:401-408.
  • 2Jeannette A,Johan W, Tapio S, et al. Interaction of kinetics and internal diffusion in complex catalytic three-phase reactions: Activity and selectivity in citral hydrogenation [J]. Chem Eng Sci,2006,61(2):814-822.
  • 3Zhan X D, Burtron H D. Assessment of internal diffusion limitation on Fischer-Tropsch product distribution [J]. Applied Catalysis, 2002,234 : 149-161.
  • 4Wakao N,Smith J M. Diffusion in catalyst pellets [J]. Chem Eng Sci, 1962,27(2) : 825-831.
  • 5Brown C E,Bennett C O. Methanol synthesis catalysis in an internally recycled reactor [J]. AIChE Journal, 1970,16 (6) : 817-823.
  • 6Cheng Chengyuan, Chen Dasheng, Ying Weiyong. Kinetics study of one-step synthesis of DME from syngas[C]//The 8th Word Congress of Chemical Engineering. Montreal,Cana da:MeGill-Queen's University Press,2009.
  • 7Brown C E,Bennett C O. Methanol synthesis catalysis in an internally recycled reactor [J]. AIChE Journal, 1970,16 (6) : 817-823.
  • 8Cheng Chengyuan, Chen Dasheng, Ying Weiyong. Kinetics study of one-step synthesis of DME from syngas[C]//The 8th Word Congress of Chemical Engineering. Montreal,Cana da:MeGill-Queen's University Press,2009.
  • 9房鼎业,姚佩芳,朱炳辰.甲醇生产技术进展[M].上海:华东化工学院出版社,1990:129—144.
  • 10Jeannette A,Johan W, Tapio S, et al. Interaction of kinetics and internal diffusion in complex catalytic three-phase reactions: Activity and selectivity in citral hydrogenation [J]. Chem Eng Sci,2006,61(2):814-822.

引证文献3

二级引证文献4

华东化工学院学报
1992年 第2期

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