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聚脲多元醇的合成研究 被引量:3

SYNTHESIS OF POLYUREA POLYOLS
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摘要 在实验室以间歇法制备了聚脲多元醇,在反应体系中加入分散剂S,研究分散剂S对体系粘度、固含量、贮存稳定性的影响,发现分散剂的加入有利于降低反应体系和产品的粘度,提高聚脲多元醇的固含量和稳定性。采用FTIR、DSC、粒径分布仪、TEM等手段分析了聚脲分散体的结构、热性能、分散性及形态。 Polyurea polyols were prepared by lab-synthesized with an organic dispersant S.The effects of the dispersant on the viscosity,solid content,stock stability of the product were researched.The method could reduce the viscosity of reactive mixture and the product,and improve solid content of the polyurea dispersion as well as stock stability of polyurea polyols.Then the structure,heat decomposition temperature,size distribution,morphological structure of the polyurea polyols were characterized by FTIR,DSC,Malvern-Autosize instrument and TEM.
出处 《热固性树脂》 CAS CSCD 2004年第3期13-16,共4页 Thermosetting Resin
关键词 聚脲多元醇 接枝共聚 分散剂 聚氨酯 polyurea polyols grafted copolymerization dispersant polyurethane
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  • 1陈竹生,程建波.聚氨酯和聚脲重要谱带的傅里叶变换红外透射光谱研究[J].烟台大学学报(自然科学与工程版),1994,7(2):41-45. 被引量:14
  • 2Dietrich. Stable dispersions of polyureas and /or polyhydrazodi-carbonamides in relatively high molecular weight, hydroxyl group-containing compounds process for the production thereof and use thereof for the production of polyurethanes[P].US Patent:47614
  • 3Reischl, Polyurethane resins produced from active hydrogen containing material which is a dispersion of polyisocyanate- polyaddition products in hydroxyl containing compounds as dispersing agents[P].US Patent:4093569,1978-06-06.
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