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Electrochemical preparation of Er-Co-Bi thin film in organic bath by cyclic electrodeposition method

Electrochemical preparation of Er-Co-Bi thin film in organic bath by cyclic electrodeposition method
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摘要 Cyclic electrodeposition was used to investigate the preparation of Er-Co-Bi alloy thin film in DMSO system. Experimental results indicate that Er-Co-Bi alloy thin film containing 14.83 %32.65 % Er is prepared from 0.1 mol/L ErCl3+0.1 mol/L CoCl2+0.1 mol/L Bi(NO3)3+0.1 mol/L LiCl +DMSO system by cyclic electrodeposition on Cu substrate. The optimum cyclic potential of electrodeposition is that upper potential is within a potential range from -0.50 V to -1.00 V and lower potential is within a potential range from -2.00 V to )-2.60 V.) The surface of alloy thin film observed by scanning electron microscope is black, adhesive and has metallic luster. The film is amorphous proved by the X-ray diffractometry. Cyclic electrodeposition was used to investigate the preparation of Er-Co-Bi alloy thin film in DMSO system. Experimental results indicate that Er-Co-Bi alloy thin film containing 14.83 %32.65 % Er is prepared from 0.1 mol/L ErCl_3+0.1 mol/L CoCl_2+0.1 mol/L Bi(NO_3)_3+0.1 mol/L LiCl +DMSO system by cyclic electrodeposition on Cu substrate. The optimum cyclic potential of electrodeposition is that upper potential is within a potential range from -0.50 V to -1.00 V and lower potential is within a potential range from -2.00 V to )-2.60 V.) The surface of alloy thin film observed by scanning electron microscope is black, adhesive and has metallic luster. The film is amorphous proved by the X-ray diffractometry.
出处 《中国有色金属学会会刊:英文版》 CSCD 2004年第2期388-391,共4页 Transactions of Nonferrous Metals Society of China
基金 Project(0 112 15 )supportedbytheNaturalScienceFoundationofGuangdongProvince,China,projectsupportedbytheStateKeyLaboratoryofRareMaterialChemistryandApplications,China
关键词 Er-Co-Bi薄膜 稀土 循环电积 电化学性能 DMSO Er-Co-Bi thin film rare earth cyclic electrodeposition dimethylsulfoxide
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参考文献15

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