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低聚合羟基铁蒙脱石复合体吸附铬酸根的实验研究 被引量:8

Experimental Study on Adsorption of Chromate on Hydroxy-Fe-montmorillonite Complex
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摘要 在模拟的酸性土壤条件下,利用制备的低聚合羟基铁 蒙脱石复合体对铬酸根进行吸附实验。重点研究了吸附条件对复合体铬吸附能力的影响,对比了蒙脱石和含水氧化铁。结果表明,实验条件下复合体有较强的铬吸附能力,其铬吸附量低于铁沉积物而明显高于蒙脱石。铬初始质量浓度是影响复合体铬吸附量的最主要因素,离子强度次之。吸附时间(12h以上)、温度、pH值对复合体铬吸附量的影响很小;说明在酸性土壤条件下,复合体有强且稳定的铬吸附能力。 Adsorption experiment of chromate has been conducted on the surface of hydroxy-Fe-montmorillonite complex under simulated acidic soil conditions. The effects of the initial concentration of chromate, ionic strength, pH, temperature and adsorption duration on the adsorption of Cr on hydroxy-Fe-montmorillonite complex have been investigated in detail. Results show that hydroxy-Fe-montmorillonite complex has strong affinity for Cr under experimental conditions.The uptake of Cr on hydroxy-Fe-montmorillonite complex is influenced by, in a decreasing order of,the initial concentration of Cr>ionic strength>temperature>adsorption duration>pH.
出处 《矿物岩石地球化学通报》 CAS CSCD 2004年第2期118-123,共6页 Bulletin of Mineralogy, Petrology and Geochemistry
基金 国家自然科学基金资助项目(49973028)
关键词 羟基铁离子 蒙脱石 复合体 铬酸根 吸附 温度 Cr污染 废弃物 hydroxy-Fe-montmorillonite complex chromate adsorption
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