金属卟啉化合物及其对烷烃的仿生催化氧化

Metalloporphyrins and Their Biomimetic Catalytic Oxidation for Alkanes

介绍了金属卟啉化合物的结构、种类及其应用 ,综述了金属卟啉化合物对烷烃的仿生催化氧化研究进展。运用金属卟啉仿生催化空气氧化环己烷制备环己酮技术 。

The structure, kinds and applications of metalloporphyrins are introduced in this paper. The recent researches on the biomimetic oxidation of alkanes catalyzed by metalloporphyrins are reviewed with the emphasis on the oxidation of cyclohexane to cyclohexanone by air. It is the first case of the industrial biomimetic oxidation for hydrocarbon with air using metalloporphyrins as catalyst.