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不对称合成中的手性膦(磷)酸酯(酰胺)催化剂

Chiral Phosphate-ester(phosphonate-ester)[phosphoramides (phosphonylamide)]Catalysts in Asymmetric Synthesis
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摘要 讨论了手性膦 (磷 )酰胺及膦 (磷 )酸酯催化剂在不对称烷基化、不对称缩合、不对称氢化、不对称氰硅化等反应中应用的最新研究进展。参考文献 4 8篇。 The advance of chiral phosphate-ester(phosphonate-ester)[phosphoramides(phosphonylamide)] in asymmetric alkylation reaction, Aldol reaction, hydrogenation reaction, cyanosilylation reaction was reviewed with 48 references.
作者 张占金 万伯顺 陈惠麟
机构地区 渤海大学化学与食品科学学院 中国科学院大连化学物理研究所精细化工研究室
出处 《合成化学》 CAS CSCD 2004年第3期237-244,272,共9页 Chinese Journal of Synthetic Chemistry
关键词 手性膦(磷)酸酯 手性膦(磷)酰胺 不对称合成 综述 chiral phosphate-ester(phosphonate-ester) chiral phosphoramides(phosphonylamide) asymmetric synthesis review
分类号 O621.3 [理学—有机化学]
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参考文献48

  • 1Brunel J M,Constantieux T,Buono G,et al. New Chiral o-hydroxyphenyl Diazaphospholidine Oxide. Catalytic Application in Asymmetric Addition of Diethylzinc to Aromatic Aldehydes[J].Tetrahedron Lett,1998,39(19):2961-2964.
  • 2Corey E J,Helal C J. Reduction of Carbonyl Compounds with Chiral Oxazaborolidine Catalysts: A New Paradigm for Enantioselective Catalysis and a Powerful New Synthetic Method[J].Angew Chem,Int Ed,1998,37(15):1986-2012.
  • 3Shi M,Sui W S. C2-Symmetric Diphenylphosphoramide and Diphenylthiophosphoramide Derived from (1R, 2R)-1,2-diaminocyclohexane as Ligands for the Titanium(Ⅳ)alkoxidepromoted Addition of Diethylzinc to Aldehydes[J].Tetrahedron:Asymmetry,1999,10(17):3319-332
  • 4Tao B,Ruble J C,Hoic D A,et al. Nonenzymatic Kinetic Resolution of Propargylic Alcohols by a Planar-Chiral DMAP Derivative:Crystallographic Characterization of the Acylated Catalyst[J].J Am Chem Soc,1999,121(21):5091-5092.
  • 5Hellwig J,Belser T,Muller J F K. A Simple Protocol for the Synthesis of Chiral Bidentate Imidodiphosphoric Tetramide Ligands:Application in the Metal-Free Asymmetric Allylation of Aldehydes[J].Tetrahedron Lett,2001,42(29):5417-5419
  • 6Denmark S E,Wynn T,Jellerichs B G. Beneficial Effect of ortho-Methoxy Groups in the Asymmetric Ring Opening of meso Epoxides with Silicon Tetrachloride Catalyzed by Chiral Ortho-methoxyphenyldiazaphosphonamide Lewis Bases[J].Angew Chem Int Ed,2001,40(12):
  • 7Denmark S E,Coe D M,Pratt N E,et al. J Asymmetric Allylation of Aldehydes with Chiral Lewis Bases[J].Org Chem,1994,59(21):6161-6163.
  • 8Iseki K,Kuroki Y,Kobayshi Y. Asymmetric Allylation of Aldehydes Catalyzed by Substoichiometric Amounts of Chiral Phosphoramides[J].Tetrahedron Lett,1996,37(29):5149-5150.
  • 9Iseki K,Kuroki Y,Takahashi M,et al. Asymmetric Allylation of Aromatic Aldehydes Catalyzed by Chiral Phosphoramides Prepared from (S)-Proline[J].Tetrahedron, 1997,53(10):3513-3526.
  • 10Denmark S E,Wong K T,Robert A,et al. The Chemistry of Trichlorosilyl Enolates. 2. Highly-Selective Asymmetric Aldol Additions of Ketone Enolates[J].J Am Chem Soc,1997,119(9):2333-2334.
合成化学
2004年 第3期

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