摘要
Ionic liquid（IL）,[bmim]PF6,was used in the reaction of one-step oxidative esterification from methacrolein to methyl methacrylate. It was found that ionic liquid not only increased the selectivity of methyl methacrylate but also inhibited its polymerization. The selectivity of methyl methacrylate was increased from 45% to 100% with ionic liquid. The experiment results showed that the content of ionic liquid had no effects on the selectivity of methyl methacrylate in a certain range of IL concentration,which indicated that ionic liquid could be used as a potential inhibitor of polymerization. [WT5HZ]
Ionic liquid(IL),[bmim]PF_6,was used in the reaction of one-step oxidative esterification from methacrolein to methyl methacrylate. It was found that ionic liquid not only increased the selectivity of methyl methacrylate but also inhibited its polymerization. The selectivity of methyl methacrylate was increased from 45% to 100% with ionic liquid. The experiment results showed that the content of ionic liquid had no effects on the selectivity of methyl methacrylate in a certain range of IL concentration,which indicated that ionic liquid could be used as a potential inhibitor of polymerization. [WT5HZ]
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2004年第6期1137-1138,共2页
Chemical Journal of Chinese Universities
基金
国家自然科学基金 (批准号 :2 0 2 760 73 )
重质油加工国家重点实验室开放基金 (批准号 :2 0 0 3 -0 5 )资助
关键词
离子液体
甲基丙烯酸甲酯
甲基丙烯醛
氧化酯化
阻聚剂
Ionic liquid
Methyl methacrylate
Methacrolein
Oxidative esterification
Polymerization inhibitor
