摘要
以纯度为84.21%的工业菲为原料,冰醋酸作溶剂,卤素化合物作为氧化剂氧化菲合成菲醌的氧化体系,菲醌最高收率可达63.23%,并确定了影响此反应的主要因素和最佳反应条件.该工艺反应条件温和,操作简单,无"三废"污染问题,溶剂可循环利用.
In the paper,phenanthrenequinone was prepared by oxidation of phenanthrene((84.21%)) with halogen compound in the presence of glacial acetic acid.The yield of phenanthrenequinone can reach 63.23%.Chief influential factors and optimum processing condition of this reaction were discussed.The reaction condition is moderate;the technological process is comparatively simple;the environment is not polluted,and the solvent can be recycled.
出处
《南华大学学报（理工版）》
2004年第2期20-24,共5页
Journal of Nanhua University(Science & Engineering)
基金
山西省教育厅科技开发项目(99011)
山西省自然科学基金资助项目(20021016).
关键词
高效液相催化
菲醌
卤素化合物
合成
氧化
phenanthrene
synthesis
phenanthrenequinone
halogen compound
