期刊文献+

固体聚合物电解质对质子交换膜燃料电池反应器的“电生”加氢特性的影响 被引量:1

EFFECT OF SOLID POLYMER ELECTROLYTE ON ELECTRO-GENERATIVE HYDROGENATION BEHAVIOR OF PEMFC REACTOR
下载PDF
导出
摘要 Effect of some solid polymer electrolyte membranes,Nafion,Gore and Fuma membrane,on the electro-generative hydrogenation behavior of the PEMFC reactor was studied.Nafion membrane has demonstrated much better performance for the electro-generative hydrogenation of organic acids and enols than Gore and Fuma membrane.For Nafion membrane,the thickness and strength both influence the hydrogenation of organic acids and enols. Effect of some solid polymer electrolyte membranes, Nafion, Gore and Fuma membrane, on the electro-generative hydrogenation behavior of the proton exchange membrane fuel cell (PEMFC) reactor was studied. Nafion membrane demonstrates much better performance for the electro-generative hydrogenation of organic acids and enols than Gore and Fuma membranes. For Nafion membrane, both the thickness and strength influence the hydrogenation of organic acids and enols.
出处 《化工学报》 EI CAS CSCD 北大核心 2004年第5期833-836,共4页 CIESC Journal
基金 国家自然科学基金 (No 2 0 0 760 2 6 No 5 0 2 3 60 10 ) 国家 863计划 (No 2 0 0 2AA3 2 3 0 40 ) 上海市国际合作项目 (No 0 2 5 2 0 70 2 1)~~
关键词 PEMFC 反应器 固体聚合物电解质 电生 加氢 Chemical reactors Hydrogenation Ion exchange membranes Organic acids Polyelectrolytes Solid electrolytes
  • 相关文献

参考文献2

二级参考文献15

  • 1马紫峰,林维明.固体电解质电化学反应器在甲烷氧化中的应用[J].天然气化工—C1化学与化工,1993,18(5):49-54. 被引量:1
  • 2马紫峰,林维明,黄仲涛.固体电解质电化学反应器中的NEMCA效应[J].化工进展,1994,13(5):45-50. 被引量:5
  • 3Stafford G R.. The Electrogenerative Partial Oxidation of Propylene[J]. Electrochimica Acta, 1987, 32(8):1137~1143.
  • 4Otsuka K, Hosokawa K, Yamanaka I, et al. One-step Oxidation of Benzene to Phenol Applying a Fuel Cell System[J]. Electrochimica Acta,1989, 34(10): 1485~1488.
  • 5Kiyoshi Otsuka, Ichiro Yamanaka. One Step Synthesis of Hydrogen Peroxide Through Fuel Cell Reaction[J]. Electrochimica Acta, 1990, 35(2):319~322.
  • 6Ishihara T, Yamada T, Akbay T, et al. Partial Oxidation of Methane over Fuel Cell Type Reactor for Simultaneous Generation of Synthesis Gas and Electric Power[J]. Chem Eng Sci, 1999, 54 (10): 1535~1540.
  • 7Tagawa T, Moe K K, Ito M, et al. Fuel Cell Type Reactor for Chemicals-energy Co-generation[J]. Chem Eng Sci, 1999, 54 (10): 1553~1557.
  • 8Langer S H, Yurchak S. Electrochemical Reduction of the Benzene Ring by Electrogenerative Hydrogenation[J]. J Electrochem Soc, 1969, 116(9):1228~1229.
  • 9Langer S H, Feiz I, Quinn C P. A Deuterium Isotope Study of Electrogenerative Hydrogenation: Mechanism of hydrogenation of ethylene at positive potentials[J]. J Am Chem Soc, 1971, 93(5):1092~1099.
  • 10Langer S H, Card J C, Foral M J. Electrogenerative and Related Process[J]. Pure & Appl Chem, 1986, 58(6):895~906.

共引文献9

同被引文献8

引证文献1

二级引证文献8

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部