过渡金属超常氧化态配离子的存在形式

Existence of Transition Metals in Highest Oxidation State Complex

对晶体和碱性介质中过渡金属超常氧化态配离子的主要存在形式和反应活化中心进行了综述,参考文献63篇.基于对过渡金属超常氧化态配离子氧化某些复杂的有机化合物的研究,提出了以低质子化程度的配离子作为反应活化中心的假设,该假设得到笔者的计算、实验结果的支持,从而否定了印度学者提出的以高质子化程度的配离子作为活化中心的假设.

The main existence of transition metals in highest oxidation state complex in crystalloid and alkaline medium and reaction activation center has been reviewed with 63 references. Based on the studies of oxidation of some complicated organic compound in our works, the hypothesis that deprotonated complexes as the activation center was proposed. It was supported by our calculated and experimental results, and in which inpeotonated complexes as the activation center the hypothesis proposed by Indian researcher was denied.