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含Eu(DBM)_3·H_2O纳米微晶的光学树脂的制备及性能研究 被引量:7

PREPARATION AND PROPERTIES OF POLYMER MATERIALS CONTAINING Eu(DBM)_3·H_2O NANOCRYSTALLINES
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摘要 Eu(DBM) 3·H 2O nanocrystallites were obtained by the chemical precipitation method.By the elemental analyzer,infrared spectrum,TGA-DSC and TEM,that the construction of nanocrystallines,the thermal properties and size were confirmed,in addition,fluorescence excitation and emission spectrum,ultraviolet absorption spectrums were investigation.Then the nanocrystallines were incorporated into the copolymer system of styrene and methyl acrylic acid,the fluorescence functional polymer nanometer material with high lanthanide content (50、wt%) were obtained.The experiment indicated that Eu(DBM) 3·H 2O nanocrystallines particle sizes were in 30~300、nm,it exhibited europium ion charlatanistic luminescence.The optical resins could provide a relatively stable environment for Eu(DBM) 3·H 2O nanocrystallines. Eu(DBM) 3·H 2O nanocrystallites were obtained by the chemical precipitation method.By the elemental analyzer,infrared spectrum,TGA-DSC and TEM,that the construction of nanocrystallines,the thermal properties and size were confirmed,in addition,fluorescence excitation and emission spectrum,ultraviolet absorption spectrums were investigation.Then the nanocrystallines were incorporated into the copolymer system of styrene and methyl acrylic acid,the fluorescence functional polymer nanometer material with high lanthanide content (50、wt%) were obtained.The experiment indicated that Eu(DBM) 3·H 2O nanocrystallines particle sizes were in 30~300、nm,it exhibited europium ion charlatanistic luminescence.The optical resins could provide a relatively stable environment for Eu(DBM) 3·H 2O nanocrystallines.
出处 《高分子学报》 SCIE CAS CSCD 北大核心 2004年第3期313-316,共4页 Acta Polymerica Sinica
基金 国家自然科学基金 (基金号 2 0 0 3 40 0 62 ) 国家重大基础性研究课题 ( 2 0 0 2CB613 40 1)资助项目
关键词 稀土配合物 光学树脂 发光材料 纳米微晶 制备 荧光性质 铕配合物 化学沉淀 Eu(DBM)3·H2O Nanocrystallines, Eu(DBM) 3·H 2O, Luminescent properties, Optical resin
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  • 1[1]Qian D J, Yang K Z, Nakahara H, Fukuda K. Langmuir, 1997,13:5925 ~ 5932
  • 2[2]Wang D M, Zhang J H, Lin Q, Fu L S,Zhang H J, Yang B. Journal of Materials Chemistry,2003,13: 2279 ~ 2284
  • 3[6]Yan B, Zhang H J, Wang S B, Ni J Z. Materials Chemistry and Physics. 1997,51:92 ~ 96
  • 4[7]Birbaun E R, Forsberg J H, Marcus Y. Gmelin Handbuch of Inorganic Chemistry (8th Edition Part D 3). Berlin, Heidelberg, New York: Springer-Verlag 1981. 194

同被引文献52

  • 1周济,苏勉曾.铕(Ⅲ)激活的磷酸镧发光性质研究[J].高等学校化学学报,1993,14(3):314-316. 被引量:13
  • 2李媛媛,闫涛,王冬梅,杜斌,魏琴.稀土配合物的发光机理及其应用[J].济南大学学报(自然科学版),2005,19(2):113-119. 被引量:14
  • 3黄春辉.稀土配位化学[M].北京:科学出版社,1999.363.
  • 4Yu Tang, Liu D B, Liu W S. Synthesis and infrared and luminescence spectra of rare earth complexes with a new hexapodal ligand [J]. Spectrochim Acta A Mol Biomol Spectrosc, 2006, 63 (1): 164.
  • 5Yu Xijuan, Song Huiyu, Zhao Huazhang. Photoacoustic amplitude and phase study on energy transfer and relaxation processes of Eu ( Ⅲ ) p-diketonate complexes [ J ]. Journal of Molecular Structure, 2002, 611: 62.
  • 6Yan Bing, Zhang Hong, Wang Shubin. Luminescence properties of .the ternary rare earth complexes withp-diketones and 1,10- phenanthroline incorporated in silica matrix by a sol-gel method [J]. Materials Chemistry and Physics, 1997, 51: 92.
  • 7Wang D M, Zhang J H, Lin Q. Lanthanide complex/polymer composite optical resin with intense narrow band emission, high transparency and goog mechanical performance [ J ]. J. Mater. Chem., 2003, 13: 2279.
  • 8SERRA O A, NASSAR E J, ZAPPAROLLI G, et al. Organic complexes of Eu^2+ supported in functionalized silica gel: Highly luminescent material [J]. Journal of Aollys and Compounds, 1994(207 208): 454-456.
  • 9徐庆红.稀土的分子筛材料的研究[D].长春:吉林大学,2000.
  • 10SHARMA P K, JILAVI M H, NASS R. Tailoring the particle size from μm→nm scale by using a surface modifier and their size effect on the fluorescence properties of europium doped yttria[J]. Journal of Luminescence, 1999, 82: 187-193.

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