摘要
Eu(DBM) 3·H 2O nanocrystallites were obtained by the chemical precipitation method.By the elemental analyzer,infrared spectrum,TGA-DSC and TEM,that the construction of nanocrystallines,the thermal properties and size were confirmed,in addition,fluorescence excitation and emission spectrum,ultraviolet absorption spectrums were investigation.Then the nanocrystallines were incorporated into the copolymer system of styrene and methyl acrylic acid,the fluorescence functional polymer nanometer material with high lanthanide content (50、wt%) were obtained.The experiment indicated that Eu(DBM) 3·H 2O nanocrystallines particle sizes were in 30~300、nm,it exhibited europium ion charlatanistic luminescence.The optical resins could provide a relatively stable environment for Eu(DBM) 3·H 2O nanocrystallines.
Eu(DBM) 3·H 2O nanocrystallites were obtained by the chemical precipitation method.By the elemental analyzer,infrared spectrum,TGA-DSC and TEM,that the construction of nanocrystallines,the thermal properties and size were confirmed,in addition,fluorescence excitation and emission spectrum,ultraviolet absorption spectrums were investigation.Then the nanocrystallines were incorporated into the copolymer system of styrene and methyl acrylic acid,the fluorescence functional polymer nanometer material with high lanthanide content (50、wt%) were obtained.The experiment indicated that Eu(DBM) 3·H 2O nanocrystallines particle sizes were in 30~300、nm,it exhibited europium ion charlatanistic luminescence.The optical resins could provide a relatively stable environment for Eu(DBM) 3·H 2O nanocrystallines.
出处
《高分子学报》
SCIE
CAS
CSCD
北大核心
2004年第3期313-316,共4页
Acta Polymerica Sinica
基金
国家自然科学基金 (基金号 2 0 0 3 40 0 62 )
国家重大基础性研究课题 ( 2 0 0 2CB613 40 1)资助项目