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C_(60)富勒烯亚氨基四氟苯甲酸苯甲酯的制备及表征 被引量：1

Synthesis and Charaterization of C_(60) fullerene Imino BenzoicTetrafluorobenzoicate
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摘要 A C60-aromatic imino derivative with novel structure was prepared by reaction of C60 with benzoic 4-azido-2,3,5,6-tetrafluorobenzoicate in chlorobenzene,at 110℃-113℃,under Ar;which was confirmed by FAB-MS,FT-IR,1H NMR,13C NMR,19F NMR,UV-vis and HPLC spectra.It cosistents with the C2v symmentry assoiated with [6,6] addition.In addition,this adduct was high stable in therm and high solubility in a solution of chloroform,toluene and acetone;It may find application as microelectronic material in biological,medical and building areas. A C_(60)-aromatic imino derivative with novel structure was prepared by reaction of C_(60) with benzoic 4-azido-2,3,5,6-tetrafluorobenzoicate in chlorobenzene,at 110℃-113℃,under Ar;which was confirmed by FAB-MS,FT-IR,~1H NMR,^(13)C NMR,^(19)F NMR,UV-vis and HPLC spectra.It cosistents with the C_(2v) symmentry assoiated with [6,6] addition.In addition,this adduct was high stable in therm and high solubility in a solution of chloroform,toluene and acetone;It may find application as microelectronic material in biological,medical and building areas.
作者 邓前军 胡晓洪 王新平
机构地区 佛山科学技术学院理学院化学与化工系
出处 《化学研究与应用》 CAS CSCD 北大核心 2004年第3期367-368,共2页 Chemical Research and Application
关键词 碳60富勒烯 制备 结构 4-叠氮基-2 3 5 6-四氟苯甲酸苯甲酯 C_(60) fullerene 4-azido-2,3,5,6-tetrafluorobenzoicate synthesis charaterization
分类号 O625.64 [理学—有机化学]
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参考文献6

  • 1[2]Hirsch A,Duber B.Acc.Chem.Res,1999,32(9):795-804.
  • 2[3]Yan M,Cai S X,Keana J F W.J.Org.Chem,1994,59(19):5951-5954.
  • 3[4]Cases M,Duran M,Sola M,et al.J.Org.Chem,2001,66(2):433-442.
  • 4[6]Prato M,Lucchihi V, Maggini M,et al. J.Am.Chem.Soc,1993,115,8479.
  • 5[7]Pasiment L,Maniero A,Ruzzi M.Chem.Commun,1999:429.
  • 6[8]Nair V,Sethurmadharan D,Sheela K C,Eigendorf G K.Tetrahedron Lett,1999,40:5087.

同被引文献32

  • 1Carravetta M,Murata Y,Murata M,et al.Solid-state NMR spectroscopy of molecular hydrogen trapped inside an open-cage fullerene[J].J Am Chem Soc,2004,126(13):4092-4093.
  • 2Iwamatsu S,Murata S,Andoh Y,et al.Open-cage fullerene derivatives suitable for the encapsulation of a hydrogen molecule[J].Journal of Organic Chemistry,2005,70(12):4820-4825.
  • 3Prat F,Stackow R,Bemstein R,et al.Triplet-state properties and singlet oxygen generation in a homologous series of functionalized fullerene derivatives[J].J Phys Chem A,1999,103(36):7230-7235.
  • 4Kitagawa T,Sakamoto H,Takeuchi K.Electrophilic addition of polychloroalkanes to C60:Direct observation of alkylfullerenyl cation intermediates[J].J Am Chem Soc,1999,121(17):4298-4299.
  • 5Huang S H,Xiao Z,Wang F D,et al.Selective preparation of oxygen-rich[60]fullerene derivatives by stepwise addition of tert-butylperoxy radical and further functionalization of the fullerene mixed peroxides[J].J Org Chem,2004,69(7):2442-2453.
  • 6Chen Z X,Wang G W.One-pot sequential synthesis of acetoxylated[60] fullerene derivatives[J].J Org Chem,2005,70(6):2380-2383.
  • 7Kitagawa T,Tanaka T,Murakita H,et al.Reversible carbon-carbon bond heterolysis of a hydrocarbon derived from tert-butylfulleride ion and tricyclopropylcyclopropenylium ion[J].J Org Chem,1999,64(1):2-3.
  • 8Brites M J,Santos C,Nascimento S,et al.Synthesis of[60]fullerene-coumarin polyads[J].Tetrahedron Letters,2004,45(37):6927-6930.
  • 9Nair V,Sethumadhavan D,Sheela K C.Dipolar cycloaddition of carbonyl ylides with[60] fullerene:Formation of novel heterocycle fused fullerene derivatives[J].Tetrahedron,2002,58(15):3009-3013.
  • 10Suzuki T,Li Q,Khemani K C,et al.Systematic inflation of buckminsterfullerene C60:Synthesis of diphenyl fulleroids C61 to C66[J].Science,1991,254(5035):1186-1188.

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化学研究与应用
2004年 第3期

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