摘要
A Zn(II) coordination polymer [Zn(pht)(pzH)2]n (where pht2-=dianion of o-phthalic acid, pzH=pyrazole) has been synthesized and the structure was determined by X-ray diffraction. The complex crystallizes in the monoclinic space group P21/c, a=0.821 39(10) nm, b=1.662 2(2) nm, c=1.156 42(14) nm, β=100.349(2)°, V=1.553 2(3) nm3, Z=4. Both carboxylate groups of the phthalate dianion coordinated in a monodentate mode bridged two Zn(II) atoms forming the structure of 1-D chain. The pyrazole ligands play two different roles: one only coordinates the metal atom and the other joins the coordination polymer into a 2-D sheet via N-H...O and C-H...O hydrogen bonds besides the coordination property. A blue photoluminescence peak at 435 nm was observed in solid state at room temperature. CCDC: 227946.
A Zn(II) coordination polymer [Zn(pht)(pzH)(2)](n) (where pht(2)=dlariion of o-phthalic acid, pzH=pyrazole) has been synthesized and the structure was determined by X-ray diffraction. The complex crystallizes in the monoclinic space group P2(1)/c, a=0.821 39(10) nm, b=1.662 2(2) nm, c=1.15642(14) nm, beta=100.349(2)degrees, V=1.553 2(3) nm(3), Z=4. Both carboxylate groups of the plithalate dianion coordinated in a monodentate mode bridged two Zn(II) atoms forming the structure of 1-D chain. The pyrazole ligands play two different roles: one only coordinates the metal atom and the other Joins the coordination polymer into a 2-D sheet via N-(HO)-O-... and C-(HO)-O-... hydrogen bonds besides the coordination property. A blue photoluminescence peak at 435 not was observed in solid state at room temperature.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2004年第7期841-844,共4页
Chinese Journal of Inorganic Chemistry
基金
南京大学大型贵重仪器设备开放测试基金资助项目。
