摘要
A series of hydrozine bridged metal halides single crystals were synthesized. Among them were [Zn(N2H4)2F2]·2H2O and [Zn(N2H4)2F]·Cl, the structures of which were characterized and shown to be 1D infinite chains. The crystal structures of the two compounds show that these 1D chains are organized into 3D structures through hydrogen bonds, and the halide anions play an important role in the stability of the crystals. The components and connecting types of these chains were compared with [Zn(N2H4)2Cl2]·2H2O to illustrate the stabilizing effect of hydrogen bonds between one dimensional chains. CSD: 413707, 1; 413708, 2.
A series of hydrozine bridged metal halides single crystals were synthesized. Among them were [Zn(N2H4)(2)F-2](.)2H(2)O and [Zn(N2H4)(2)F]Cl-., the structures of which were characterized and shown to be 1D infinite chains. The crystal structures of the two compounds show that these 1D chains are organized into 3D structures through hydrogen bonds, and the halide anions play an important role in the stability of the crystals. The components and connecting types of these chains were compared with [Zn(N2H4)(2)Cl-2](.)2H(2)O to illustrate the stabilizing effect of hydrogen bonds between one dimensional chains.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2004年第7期819-823,共5页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金(No.20025102
50028201
20151001)
全国优秀博士论文基金
国家重大基础研究发展规划"973"项目(No.G19990645-03)等多项基金资助项目。
