高超音速钝头体绕流反应速率与壁面催化问题

THE EFFECTS OF REACTION RATE CONSTANTS AND CATALYTIC WALL ON THE HYPERSONIC FLOW FIELD OVER BLUNT BODIES

反应速率与壁面催化是反应流中两个重要问题。本文以高超音速化学反应钝头体绕流为例对这两个问题做了初步的分析和讨论。反应速率问题实质上是反应速率常数实验数据的误差及其影响,本文根据实验数据的分散度大小以样本数据组和等效速率常数不确定性因子这两个概念建立反应速率常数分析数据库,通过对数据误差和计算结果的分析与比较总结出高超音速钝体绕流高温特性与化学反应特性计算结果依赖于反应速率数据库的某些规律。壁面催化问题是固壁对与之接触的气体化学反应的催化影响,通过引入一个新的壁面催化率参数来考虑壁面催化性质对高超音速钝体绕流计算结果的影响。由于引入和强化了上述概念,给化学反应速率与壁面催化问题的分析与研究提供了有力的手段,因而提高了数值模拟结果的可信度。

Some fundmental analysis and discusion has been made about the reaction rate constants and catalytic wall involved in the numerical solution for the hypersonic viscous shock layer flow fields over blunt bodies. The ideas of sample rate constants and affecting deviation factor have been proposed in order to build the chemical reaction rate data library for the given chemical reaction system.