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二氟甲烷分子3a_1和2b_2轨道的电子动量谱 被引量:1

Electron Momentum Spectroscopy of Inner Valence Orbitals 3a_1 and 2b_2 of Methylene Fluoride
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摘要 The electron momentum spectroscopy of the inner valence orbitals 3a 1 and 2b 2 of methylene fluoride was studied by electron momentum spectroscopy(EMS). The experiment was performed using a high resolution(ΔE=1.15 eV FWHM, Δp=0.1 a.u.)(e,2e) EMS spectrometer. The experimental momentum profiles of these two orbitals are compared with those calculated by Hartree-Fork method and Density Functional Theory. The electron momentum spectroscopy of the inner valence orbitals 3a 1 and 2b 2 of methylene fluoride was studied by electron momentum spectroscopy(EMS). The experiment was performed using a high resolution(ΔE=1.15 eV FWHM, Δp=0.1 a.u.)(e,2e) EMS spectrometer. The experimental momentum profiles of these two orbitals are compared with those calculated by Hartree-Fork method and Density Functional Theory.
机构地区 清华大学物理系
出处 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2004年第3期233-235,共3页 化学物理学报(英文)
基金 ProjectsupportedbytheNationalNaturalScienceFoundationofChina (1985 4 0 0 2 19774 0 37 10 2 74 0 4 0 )
关键词 二氟甲烷 电子动量谱 Hartree-Fork DFT Methylene fluoride, Electron momentum spectroscopy, Hartree-Fork, DFT
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