水杨醛缩氨基酸希夫碱异双核配合物催化氧化烯烃性能的研究

Study on the catalytic oxidation properties of the heterometal binuclear complexes

在温和条件下,用水杨醛缩氨基酸希夫碱异双核配合物作为催化剂,以分子氧为氧化剂,研究了对环己烯、1 辛烯、1 癸烯的选择氧化反应,结果表明它们均有良好的催化活性.

Under mild conditions, salicyaldehyde amino acids Schiff base heterometal binuclear complexes( Sal-aa-M-M′) (aa=β-Ala,L-Phe,L-Glu ; M= Co-(2+_,M′= Cu-(2+_,Mn-(2+_ )are applied for catalyzing selective oxidation of olefins by O2. It is found that binuclear complexes show higher catalytic activities.