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CHARACTERISTICS OF LIGNIN REACTIONS IN SODA COOKING OF WHEAT STRAW PART 1 REACTION OF UNCONDENSED LIGNIN

CHARACTERISTICS OF LIGNIN REACTIONS IN SODA COOKING OF WHEAT STRAW PART 1 REACTION OF UNCONDENSED LIGNIN
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摘要 Characteristics of uncondensed lignin reactions in soda cooking of wheat straw were studied. Mild and intense cooking conditions were used to get the pulp sample in which lignin was dissolved physically and the pulp sample in which lignin was dissolved chemically respectively. The pulp samples were analyzed by phenolic group determination, alkaline nitrobenzene oxidation and ozonation method. The results indicated that around 90% of lignin in wheat straw is alkali-soluble at the mild conditions, is basically dissolved physically without chemical change. The phenolic group content was not changed greatly, the nitrobenzene oxidation yield only changed slightly during the mild cooking. The phenolic group content was increased obviously and uncondensed lignin content was decreased very much when the intense cooking conditions were applied and the delignification was over 90%. The lignin structure was changed greatly during this period. Characteristics of uncondensed lignin reactions in soda cooking of wheat straw were studied. Mild and intense cooking conditions were used to get the pulp sample in which lignin was dissolved physically and the pulp sample in which lignin was dissolved chemically respectively. The pulp samples were analyzed by phenolic group determination, alkaline nitrobenzene oxidation and ozonation method. The results indicated that around 90% of lignin in wheat straw is alkali-soluble at the mild conditions, is basically dissolved physically without chemical change. The phenolic group content was not changed greatly, the nitrobenzene oxidation yield only changed slightly during the mild cooking. The phenolic group content was increased obviously and uncondensed lignin content was decreased very much when the intense cooking conditions were applied and the delignification was over 90%. The lignin structure was changed greatly during this period.
出处 《天津科技大学学报》 CAS 2004年第A02期115-118,共4页 Journal of Tianjin University of Science & Technology
关键词 小麦秸杆 木质素反应 苏打 碱性烹饪 不凝结木质素 纸浆 臭氧分析 Wheat straw, Alkaline cooking, Lignin, Ozone analysis, β- O - 4 ether linkage, Phenolic group
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