两个基于1-三氮唑-4-四氮唑苯的配位聚合物的合成、结构及荧光性

Synthesis, Structure and Fluorescence of Two Coordination Polymers Based on 1-Triazole-4-Tetrazole Benzene

近年来,多孔配位聚合物在气体储存、分离以及复合光、电、磁等多功能领域具有诱人的前景而备受关注。本文主要采用1-三氮唑-4-四氮唑苯有机配体分别与铜(I)、银(I)离子自组装得到2个新颖的配位聚合物,并对其组装规律和构效关系进行探索。

Recently, porous coordination polymers (PCPs) have attracted great interest on account of their potential application in gas storage and separation, and as optoelectronic and magnetic materials. In this work, by utilizing the 1-Triazole-4-Tetrazole Benzene ligands with copper (I) salt and silver (I), we have successfully constructed two novel PCPs. Efforts have been focused on the exploration of self-assembly and the relationship between structures and properties.