惰性烯丙基试剂参与的不对称烯丙基化反应研究进展

Advances in Asymmetric Allylation Reactions Involving Unactivated Allyl Reagents

过渡金属催化的不对称烯丙基化反应近年来已成为合成具有光学活性的手性化合物的重要方法。本文对近年来惰性烯丙基试剂如烯丙醇、胺、醚及联烯醚参与的不对称烯丙基化反应进行简要评述,并对该类反应未来发展前景及方向进行展望。

Transition-metal-catalyzed asymmetric allylation reactions have become an important method for the synthesis of optically active chiral compounds in recent years.In this paper,the asymmetric allylation reactions involving unactivated allyl reagents such as allyl alcohols,amines,ethers and allenes are briefly reviewed,and the future development prospects and directions of these reac-tions are prospected.