MOF/COF复合材料合成与应用研究进展

Research Progress on Synthesis and Application of MOF/COF Composites

金属有机骨架材料(MOF)和共价有机骨架材料(COF)因结构易调控、具有较大的比表面积和高孔隙率等优点逐渐成为材料研究领域的热点。但MOF和COF自身仍存在不足,将不同类型的MOF和COF材料进行有效复合,不仅可以保持各自的优势,还可以解决各自存在的不足,在各种应用中表现出优异的潜力。因此,基于MOF/COF的复合材料得到了越来越多的关注和快速发展。本文主要论述了MOF/COF复合材料的合成方法及其在吸附和分离、光催化、传感和储能领域的应用。

Metal organic frameworks (MOF) and covalent organic frameworks (COF) have gradually become hot spots in the field of materials research due to the advantages of easy structural adjustment, large specific surface area and high porosity. However, MOF and COF still have their own shortcomings, and the effective compounding of different types of MOF and COF materials can not only maintain their re-spective advantages, but also solve their respective shortcomings. The composites have shown ex-cellent potential in various applications. Therefore, MOF/COF composites have received more and more attention and rapid development. In this paper, the synthetic strategies of MOF/COF compo-sites and their applications in adsorption and separation, photocatalysis, sensing and energy stor-age are discussed.