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Improvement of the Cycle Performance of LiNi<sub>0.5</sub>Mn<sub>1.5</sub>O<sub>4 </sub>Cathode Active Materials by In-Situ Coating with Poly(3,4-Ethylenedioxythiophene)

Improvement of the Cycle Performance of LiNi<sub>0.5</sub>Mn<sub>1.5</sub>O<sub>4 </sub>Cathode Active Materials by In-Situ Coating with Poly(3,4-Ethylenedioxythiophene)
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摘要 LiNi0.5Mn1.5O4 (LNMO)/poly(3,4-ethylenedioxythiophene) (PEDOT) composite cathode materials were prepared through in-situ polymerization of thiophene monomer (EDOT), with ammonium persulphate (APS) as oxidizing agent, p-toluenesulfonic acid (PTSA) as dopant. The morphology, amount of PEDOT coating, electrochemical properties of LNMO/PEDOT were characterized by scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and galvanostatic charge and discharge tests. The results show that the composite materials show better cycle performance than bare LNMO. LiNi0.5Mn1.5O4 (LNMO)/poly(3,4-ethylenedioxythiophene) (PEDOT) composite cathode materials were prepared through in-situ polymerization of thiophene monomer (EDOT), with ammonium persulphate (APS) as oxidizing agent, p-toluenesulfonic acid (PTSA) as dopant. The morphology, amount of PEDOT coating, electrochemical properties of LNMO/PEDOT were characterized by scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and galvanostatic charge and discharge tests. The results show that the composite materials show better cycle performance than bare LNMO.
出处 《Journal of Power and Energy Engineering》 2017年第12期28-32,共5页 电力能源(英文)
关键词 LITHIUM-ION Battery LiNi0.5Mn1.5O4PEDOT In-Situ Coating Lithium-Ion Battery LiNi0.5Mn1.5O4PEDOT In-Situ Coating
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