摘要
In this work, an analysis of the regularities of the electrolytic dissociation of aryl derivatives of the succinic acid (phenylsuccinic, benzylsuccinic, dibenzylsuccinic and phenyl-2-benzylsuccinic acids) in their dilute (0.0001 - 0.01 mol.dm-3) solutions was carried out with the aid of a new method of determination of the dissociation parameters of weak multibasic organic acids with the “overlapping equilibria” effect previously described by authors. Values of the usual and “partial” degrees of dissociation, the concentrations of all anions, hydrogen ions and undissociated acid molecules, the activity coefficients of all charged dissociation products were calculated. Together with the accurate equations, the simple empirical equations for fast approximate determination of the various dissociation parameters were also suggested.
In this work, an analysis of the regularities of the electrolytic dissociation of aryl derivatives of the succinic acid (phenylsuccinic, benzylsuccinic, dibenzylsuccinic and phenyl-2-benzylsuccinic acids) in their dilute (0.0001 - 0.01 mol.dm-3) solutions was carried out with the aid of a new method of determination of the dissociation parameters of weak multibasic organic acids with the “overlapping equilibria” effect previously described by authors. Values of the usual and “partial” degrees of dissociation, the concentrations of all anions, hydrogen ions and undissociated acid molecules, the activity coefficients of all charged dissociation products were calculated. Together with the accurate equations, the simple empirical equations for fast approximate determination of the various dissociation parameters were also suggested.
