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Ultrasonic Activation of Suzuki and Hiyama Cross-Coupling Reactions Catalyzed by Palladium

Ultrasonic Activation of Suzuki and Hiyama Cross-Coupling Reactions Catalyzed by Palladium
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摘要 The coupling reaction of aryl bromide and aryl boronic acid in water/DMF as solvent was studied using a palladium-complex as a catalyst in the presence of ultrasound at room temperature. The effect on the reaction of a base and a solvent was also studied with and without ultrasound and was found to increase the speed of the reaction. In this regard, we propose reaction mechanisms that could explain the results obtained. The coupling reaction of aryl bromide and aryl boronic acid in water/DMF as solvent was studied using a palladium-complex as a catalyst in the presence of ultrasound at room temperature. The effect on the reaction of a base and a solvent was also studied with and without ultrasound and was found to increase the speed of the reaction. In this regard, we propose reaction mechanisms that could explain the results obtained.
作者 Khemais Said Ridha Ben Salem Khemais Said;Ridha Ben Salem(Physical Organic Chemistry Laboratory (UR11ES74), Science Faculty of Sfax, University of Sfax, Sfax, Tunisia)
出处 《Advances in Chemical Engineering and Science》 2016年第2期111-123,共13页 化学工程与科学期刊(英文)
关键词 PALLADIUM Suzuki Cross-Coupling Hiyama ULTRASOUND Sonochemical Activation Palladium Suzuki Cross-Coupling Hiyama Ultrasound Sonochemical Activation
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