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A Comparative Assessment of Hydrogen Embrittlement: Palladium and Palladium-Silver (25 Weight% Silver) Subjected to Hydrogen Absorption/Desorption Cycling

A Comparative Assessment of Hydrogen Embrittlement: Palladium and Palladium-Silver (25 Weight% Silver) Subjected to Hydrogen Absorption/Desorption Cycling
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摘要 The negative effects of hydrogen embrittlement on metallic systems have been investigated through determination of the mechanical properties of two metallic systems that were exposed to hydrogen. An assessment of the effects of hydrogen absorption/desorption cycling on the tensile strength, ductility, and microhardness of pure palladium and the alloy palladium-silver (25 weight% silver) has been undertaken. The variables that are the focus of the study are the amount of hydrogen absorbed by the metal, deuterium isotope effect, number of hydrogen absorption/desorption cycles, and the hydrogen exposure temperature. Under all conditions studied, the mechanical properties of pure palladium were significantly altered as a result of hydrogen exposure, with significant hydrogen embrittlement occurring. In contrast, the mechanical properties of the palladium-silver alloy showed little alteration as a result of hydrogen exposure, including virtually no occurrence of hydrogen embrittlement. The negative effects of hydrogen embrittlement on metallic systems have been investigated through determination of the mechanical properties of two metallic systems that were exposed to hydrogen. An assessment of the effects of hydrogen absorption/desorption cycling on the tensile strength, ductility, and microhardness of pure palladium and the alloy palladium-silver (25 weight% silver) has been undertaken. The variables that are the focus of the study are the amount of hydrogen absorbed by the metal, deuterium isotope effect, number of hydrogen absorption/desorption cycles, and the hydrogen exposure temperature. Under all conditions studied, the mechanical properties of pure palladium were significantly altered as a result of hydrogen exposure, with significant hydrogen embrittlement occurring. In contrast, the mechanical properties of the palladium-silver alloy showed little alteration as a result of hydrogen exposure, including virtually no occurrence of hydrogen embrittlement.
作者 Gilberto Jimenez Erik Dillon Joseph Dahlmeyer Travis Garrison Tyler Garrison Sedna Darkey Kyle Wald Joseph Kubik Danielle Paciulli Mustakim Talukder Joshua Nott Maria Ferrer Joseph Prinke Priscilla Villaneuva Fred Massicotte Karim Rebeiz Steve Nesbit Andrew Craft Gilberto Jimenez;Erik Dillon;Joseph Dahlmeyer;Travis Garrison;Tyler Garrison;Sedna Darkey;Kyle Wald;Joseph Kubik;Danielle Paciulli;Mustakim Talukder;Joshua Nott;Maria Ferrer;Joseph Prinke;Priscilla Villaneuva;Fred Massicotte;Karim Rebeiz;Steve Nesbit;Andrew Craft(Department of Chemistry, University of Hartford, West Hartford, CT, USA;Institute of Materials Science, University of Connecticut, Storrs, CT, USA;College of Engineering, Phoenicia University, Beirut, Lebanon;Department of Mechanical Engineering, Lafayette College, Easton, PA, USA)
出处 《Advances in Chemical Engineering and Science》 2016年第3期246-261,共17页 化学工程与科学期刊(英文)
关键词 Hydrogen PALLADIUM Palladium-Silver EMBRITTLEMENT Hydrogen Palladium Palladium-Silver Embrittlement
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