摘要
The copolymer of the maleic anhydride-styrene is modified at the presence of 4-amino-2-thiouracil and formaldehyde and the new polymeric sorbate with spatial structure is received. The received sorbate is identified by the IR-spectroscopy method. The complete static sorption capacitance was studied (CSSC<sup>+</sup>K</sub>= 7.8 mmol/g) and the ionization constants of ionic groups in a sorbate link was defined by electrometric method. Ionization constants were determined by potentiometric titration of the sorbent (). Sorption and desorption of the received sorbent with a lead ion (II) are investigated and optimum concentration conditions are defined: рН<sub>opt.</sub> = 5, ionic force μ = 0.8 pier/l, full sorption balance 4 hours, optimum eluent 5 ml of 0.5 M HCl.
The copolymer of the maleic anhydride-styrene is modified at the presence of 4-amino-2-thiouracil and formaldehyde and the new polymeric sorbate with spatial structure is received. The received sorbate is identified by the IR-spectroscopy method. The complete static sorption capacitance was studied (CSSC<sup>+</sup>K</sub>= 7.8 mmol/g) and the ionization constants of ionic groups in a sorbate link was defined by electrometric method. Ionization constants were determined by potentiometric titration of the sorbent (). Sorption and desorption of the received sorbent with a lead ion (II) are investigated and optimum concentration conditions are defined: рН<sub>opt.</sub> = 5, ionic force μ = 0.8 pier/l, full sorption balance 4 hours, optimum eluent 5 ml of 0.5 M HCl.
作者
R. A. Aliyeva
N. S. Huseynova
Ulviya M. Abilova
G. B. İskandarov
F. M. Chiragov
R. A. Aliyeva;N. S. Huseynova;Ulviya M. Abilova;G. B. İskandarov;F. M. Chiragov(Department of Analytical Chemistry, Faculty of Chemistry, Baku State University, Baku, Azerbaijan;Department of the General and Toxicological Chemistry, Faculty of Pharmacology, Azerbaijan Medical University, Baku, Azerbaijan)
