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Preparation of Dithienylethene with Amino Groups, and Photochromic Behavior in Langmuir-Blodgett Film of the Amphiphilicdithienylethene

Preparation of Dithienylethene with Amino Groups, and Photochromic Behavior in Langmuir-Blodgett Film of the Amphiphilicdithienylethene
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摘要 We successfully synthesized dithienylethene with amino groups. Then, we successfully prepared Langmuir-Blodgett (LB) films of the dithienylethene having ammonium cation group when dodecyl benzene sulfonic acid was employed as an anionic counter ion. From X-ray diffraction profiles, however, it was demonstrated that they did not form well-defined layered structure;X-ray diffraction peaks were much broadened. Photochromic behavior was confirmed in the LB films. Unfortunately, the LB films were not so stable;photochromic reaction was observed only several times in the LB films. We successfully synthesized dithienylethene with amino groups. Then, we successfully prepared Langmuir-Blodgett (LB) films of the dithienylethene having ammonium cation group when dodecyl benzene sulfonic acid was employed as an anionic counter ion. From X-ray diffraction profiles, however, it was demonstrated that they did not form well-defined layered structure;X-ray diffraction peaks were much broadened. Photochromic behavior was confirmed in the LB films. Unfortunately, the LB films were not so stable;photochromic reaction was observed only several times in the LB films.
出处 《International Journal of Organic Chemistry》 2013年第2期158-161,共4页 有机化学国际期刊(英文)
关键词 AMPHIPHILIC DITHIENYLETHENE LANGMUIR-BLODGETT Film PHOTOCHROMIC Material Dodecyl Benzenesulfonic ACID Amphiphilic Dithienylethene Langmuir-Blodgett Film Photochromic Material Dodecyl Benzenesulfonic Acid
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