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Electrical Transport Properties of Bi<sub>2</sub>O<sub>3</sub>-Doped CoFe<sub>2</sub>O<sub>4</sub>and CoHo<sub>0.02</sub>Fe<sub>1.98</sub>O<sub>4</sub>Ferrites

Electrical Transport Properties of Bi<sub>2</sub>O<sub>3</sub>-Doped CoFe<sub>2</sub>O<sub>4</sub>and CoHo<sub>0.02</sub>Fe<sub>1.98</sub>O<sub>4</sub>Ferrites
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摘要 Two series of CoHoxFe2-x O4 (x = 0.0,0.02) ferrites with Bismuth oxide doping from (0.1-0.3)% were prepared by Co-precipitation technique. X-ray diffraction analysis revealed fcc structure. The lattice constants were found to decrease as the doping of Bi2O3increases in both series. An increase in Bismuth oxide concentration from (0.1-0.3%) in CoFe2O4, and CoHo0.02Fe1.98O4ferrites leads to an increase in room temperature resistivity. Temperature dependent resistivity decreases as the temperature increases following the Arrhenius equation. The activation energy increases with the increase of Bi2O3-concentration for both CoFe2O4 and CoHo0.02Fe1.98O4series. The frequency dependant dielectric constant follows the Maxwell-Wagner type interfacial polarization. The dielectric loss indicates the normal behavior of these ferrites. SEM analysis shows an increase in grain size with increasing Bismuth concentration. Two series of CoHoxFe2-x O4 (x = 0.0,0.02) ferrites with Bismuth oxide doping from (0.1-0.3)% were prepared by Co-precipitation technique. X-ray diffraction analysis revealed fcc structure. The lattice constants were found to decrease as the doping of Bi2O3increases in both series. An increase in Bismuth oxide concentration from (0.1-0.3%) in CoFe2O4, and CoHo0.02Fe1.98O4ferrites leads to an increase in room temperature resistivity. Temperature dependent resistivity decreases as the temperature increases following the Arrhenius equation. The activation energy increases with the increase of Bi2O3-concentration for both CoFe2O4 and CoHo0.02Fe1.98O4series. The frequency dependant dielectric constant follows the Maxwell-Wagner type interfacial polarization. The dielectric loss indicates the normal behavior of these ferrites. SEM analysis shows an increase in grain size with increasing Bismuth concentration.
机构地区 Department of Physics
出处 《Materials Sciences and Applications》 2011年第8期1083-1089,共7页 材料科学与应用期刊(英文)
关键词 Cobalt Ferrites CO-PRECIPITATION BI Doping Electrical Properties Cobalt Ferrites Co-Precipitation Bi Doping Electrical Properties
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