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The Role of Valence Electron Concentration on the Structure and Properties of Rapidly Solidified Sn-Ag Binary Alloys

The Role of Valence Electron Concentration on the Structure and Properties of Rapidly Solidified Sn-Ag Binary Alloys
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摘要 A group of binary Sn-xAg alloys (x = 0.5, 1.5, 2.5, 3.5, 4.5, 5.5 and 6.5 wt%) has been produced by a single copper roller melt-spinning technique. In this study the interaction between Fermi sphere and Brillouin zone and Hume-Rothery condition of phase stability have been verified. It is found that by increasing valence electron concentration VEC the diameter of Fermi sphere 2kF increases which leads to the increase in the diameter of Brillouin zone which arises from the decrease in volume of the unit cell. It is found that the electrical resistivity increases by increasing VEC due to the decrease in relaxation time τ with increasing VEC. Also it has been confirmed that the correlation between Young’s modulus and the axial ratio c/a of β-Sn unit cell. A group of binary Sn-xAg alloys (x = 0.5, 1.5, 2.5, 3.5, 4.5, 5.5 and 6.5 wt%) has been produced by a single copper roller melt-spinning technique. In this study the interaction between Fermi sphere and Brillouin zone and Hume-Rothery condition of phase stability have been verified. It is found that by increasing valence electron concentration VEC the diameter of Fermi sphere 2kF increases which leads to the increase in the diameter of Brillouin zone which arises from the decrease in volume of the unit cell. It is found that the electrical resistivity increases by increasing VEC due to the decrease in relaxation time τ with increasing VEC. Also it has been confirmed that the correlation between Young’s modulus and the axial ratio c/a of β-Sn unit cell.
出处 《Materials Sciences and Applications》 2012年第3期179-184,共6页 材料科学与应用期刊(英文)
关键词 Alloys Rapid Solidification VALENCE Electron CONCENTRATION Resistivity Young’s Modulus FERMI Energy BRILLOUIN Zone Alloys Rapid Solidification Valence Electron Concentration Resistivity Young’s Modulus Fermi Energy Brillouin Zone
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