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Band Gap Determination from Diffuse Reflectance Measurements of Irradiated Lead Borate Glass System Doped with TiO<sub>2</sub>by Using Diffuse Reflectance Technique 被引量:3

Band Gap Determination from Diffuse Reflectance Measurements of Irradiated Lead Borate Glass System Doped with TiO<sub>2</sub>by Using Diffuse Reflectance Technique
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摘要 Ultraviolet-visible UV-Vis diffuse reflectance measurements of irradiated lithium tetra-borate glass have been acquired using. Evolution 600 Spectrophotometer equipped with praying Mantis Diffuse Reflectance Accessory DRA base upon the onset of the diffuse reflectance spectra of the powdered or bulk materials. Also the absorption edge and band gap energies of the prepared glass were determined. The optical energy gap is calculated and found to be (3.0 - 3.5) eV. Which is in close agreement to the one calculated for r = 1/2, i.e. the transition mechanism, is accordingly direct allowed transition. The density increases from 3.1 to 3.9 gm/cm3 for the undoped and doped glass. Ultraviolet-visible UV-Vis diffuse reflectance measurements of irradiated lithium tetra-borate glass have been acquired using. Evolution 600 Spectrophotometer equipped with praying Mantis Diffuse Reflectance Accessory DRA base upon the onset of the diffuse reflectance spectra of the powdered or bulk materials. Also the absorption edge and band gap energies of the prepared glass were determined. The optical energy gap is calculated and found to be (3.0 - 3.5) eV. Which is in close agreement to the one calculated for r = 1/2, i.e. the transition mechanism, is accordingly direct allowed transition. The density increases from 3.1 to 3.9 gm/cm3 for the undoped and doped glass.
出处 《Materials Sciences and Applications》 2013年第5期324-329,共6页 材料科学与应用期刊(英文)
关键词 Diffuse Reflectance ACCESSORY Optical Gap Borate-Lead-Titanium-Glasses Gamma Radiation Diffuse Reflectance Accessory Optical Gap Borate-Lead-Titanium-Glasses Gamma Radiation
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