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Effect of Carbon Graphite on the Crystallization of Andalusite: Application to the Synthesis of Mullite and the Improvement of Refractory Quality 被引量:2

Effect of Carbon Graphite on the Crystallization of Andalusite: Application to the Synthesis of Mullite and the Improvement of Refractory Quality
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摘要 Different mixtures of Moroccan silica-alumina geomaterials were used for the preparation of refractory ceramics. A formula of composition (M2) has allowed obtaining a good quality of refractory. Addition of a small quantity of carbon (1%) to the M2 formula has substantially improved the quality of the refractory. The morphological, textural and mineralogical evolution, through SEM and XRD shows that the addition of carbon, which plays a catalytic role, favors the crystallization of andalusite. Then, from 1200°C, the andalusite starts to transform to primary mullite needles. At 1400°C, the mullite becomes the major mineral phase beside cristobalite and vitreous phase. Different mixtures of Moroccan silica-alumina geomaterials were used for the preparation of refractory ceramics. A formula of composition (M2) has allowed obtaining a good quality of refractory. Addition of a small quantity of carbon (1%) to the M2 formula has substantially improved the quality of the refractory. The morphological, textural and mineralogical evolution, through SEM and XRD shows that the addition of carbon, which plays a catalytic role, favors the crystallization of andalusite. Then, from 1200°C, the andalusite starts to transform to primary mullite needles. At 1400°C, the mullite becomes the major mineral phase beside cristobalite and vitreous phase.
出处 《Materials Sciences and Applications》 2013年第6期337-346,共10页 材料科学与应用期刊(英文)
关键词 REFRACTORY Alumina-Silica ANDALUSITE MULLITE Morocco Refractory Alumina-Silica Andalusite Mullite Morocco
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