摘要
Novel triblock copolymers of poly (L-lactide)-poly (ethylene glycol)-sebacate-poly (ethylene glycol)-poly (L-lactide) were synthesized by Ring-Opening Polymerization of different ratios of L-lactide with other three pre-prepared poly (ethylene glycol)-sebacate-poly (ethylene glycol) polymers, coded A, B and C which had different poly (ethyleneglycol) chain lengths. The copolymers were characterized by FTIR and <sup>1</sup>H NMR spectroscopy, which indicated that the reaction of ROP took place and led to producing nine triblock copolymers having new different lactide chain lengths (n = 10, 25 and 50), AL<sub>10</sub>, AL<sub>25</sub>, AL<sub>50</sub>,BL<sub>10</sub>, BL<sub>25</sub>, BL<sub>50</sub>, CL<sub>10</sub>, CL<sub>25</sub>, and CL<sub>50</sub>. Nine polymer networks were also prepared from copolymers with sodium alginate S<sub>1</sub> - S<sub>9</sub> and finally mixed with a solution of hydroxyl ethyl cellulose to form SH<sub>1</sub> - SH<sub>9</sub>.
Novel triblock copolymers of poly (L-lactide)-poly (ethylene glycol)-sebacate-poly (ethylene glycol)-poly (L-lactide) were synthesized by Ring-Opening Polymerization of different ratios of L-lactide with other three pre-prepared poly (ethylene glycol)-sebacate-poly (ethylene glycol) polymers, coded A, B and C which had different poly (ethyleneglycol) chain lengths. The copolymers were characterized by FTIR and <sup>1</sup>H NMR spectroscopy, which indicated that the reaction of ROP took place and led to producing nine triblock copolymers having new different lactide chain lengths (n = 10, 25 and 50), AL<sub>10</sub>, AL<sub>25</sub>, AL<sub>50</sub>,BL<sub>10</sub>, BL<sub>25</sub>, BL<sub>50</sub>, CL<sub>10</sub>, CL<sub>25</sub>, and CL<sub>50</sub>. Nine polymer networks were also prepared from copolymers with sodium alginate S<sub>1</sub> - S<sub>9</sub> and finally mixed with a solution of hydroxyl ethyl cellulose to form SH<sub>1</sub> - SH<sub>9</sub>.
