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Interpretation of Adsorption Thermodynamics and Kinetics

Interpretation of Adsorption Thermodynamics and Kinetics
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摘要 A complete study of adsorption processes will be less complete if the structure and dynamics of its different elements and how they interact is not well captured. Therefore, the extensive study of adsorption thermodynamics in conjunction with adsorption kinetics is inevitable. Measurable thermodynamic </span><span style="font-family:Verdana;">properties such as temperature equilibrium constant and their non-measurable</span><span style="font-family:Verdana;"> counterparts such as Gibbs free energy change, enthalpy, entropy etc. are very important design variables usually deployed for the evaluation and prediction of the mechanism of adsorption processes. A complete study of adsorption processes will be less complete if the structure and dynamics of its different elements and how they interact is not well captured. Therefore, the extensive study of adsorption thermodynamics in conjunction with adsorption kinetics is inevitable. Measurable thermodynamic </span><span style="font-family:Verdana;">properties such as temperature equilibrium constant and their non-measurable</span><span style="font-family:Verdana;"> counterparts such as Gibbs free energy change, enthalpy, entropy etc. are very important design variables usually deployed for the evaluation and prediction of the mechanism of adsorption processes.
作者 Augustus Newton Ebelegi Nimibofa Ayawei Donbebe Wankasi Augustus Newton Ebelegi;Nimibofa Ayawei;Donbebe Wankasi(Department of Chemical Sciences, Niger Delta University, Wilberforce Island, Nigeria)
出处 《Open Journal of Physical Chemistry》 2020年第3期166-182,共17页 物理化学期刊(英文)
关键词 Gibbs Free Energy Entropy Change Adsorption Density Sticking Probability Activation Energy Pseudo-Second-Order Kinetic Model Elovich Model Brouers-Sotolongo Fractal Kinetic Model Gibbs Free Energy Entropy Change Adsorption Density Sticking Probability Activation Energy Pseudo-Second-Order Kinetic Model Elovich Model Brouers-Sotolongo Fractal Kinetic Model
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